英语翻译
Inthepresenttreatment,justoneexperimentalvalueis
neededtoevaluatetheoxideionpolarizabilityaO23and
opticalbasicityL,thatis,theenergygapEgorrefractive
indexn.Thereisnomodelsofarinvolvingoptical
electronegativityDw2glassasaparameterinobtainingthe
opticalbasicityLandelectronicpolarizabilityaO23values
ofbinaryoxideglasses.WefindEqs.(4)and(5)suitablefor
theestimationoftheopticalbasicityLandelectronic
polarizabilityaO23.Thesimplicityofthepresentstudyisto
estimatetheopticalbasicityLandelectronicpolarizability
aO23valuesfordifferentbinaryoxideglasses,justone
experimentalvalueisneeded,thatis,theopticalelectronegativity
valuesDw2glass.TheestimatedopticalbasicityL
andelectronicpolarizabilityaO23ofbinaryoxideglasses
basedonDw2narepresentedinTable1(columns11and13).
Forcomparisons,thevaluesofDimitrovandKomatsu[10]
arealsoincludedinthesametable(columns10and12)
ThecalculatedvaluesofelectronicpolarizabilityaO23and
opticalbasicityLareplottedagainsttheexperimental
valuesinFigs.3and4,respectively.Agoodagreementcan
beobservedbetweentheelectronicpolarizabilityaO23and
opticalbasicityLvaluesobtainedwithdifferentinitial
quantities.
OurestimatedoxideionpolarizabilityaO23andoptical
basicityLvaluesusingtheopticalelectronegativityDw2glass
(Eqs.(4)and(5))deviateslightlyfromthevaluesof
DimitrovandKomatsu[10]inthecaseofPbO3P2O5,
PbO3B2O3,andPbO–SiO2.ForRnOm3TiO2(R¼K2O,
Rb2O,andPbO)compositions,theestimatedoxideion
polarizabilityaO23andopticalbasicityLvaluesusing
Eqs.(4)and(5)athigherfirstoxidepercentagedeviate
moreincomparisonwiththevaluesofDimitrovand
Komatsu[10].Afairagreementhasbeenobservedbetween
thesevaluesintherestofthecomposition.Thismeansthat
thedeterminationofoxid